Poly[μ-1,3-thiazolidine-2-thione-κ2 S 2:S 2-μ-thiocyanato-κ2 S:N-copper(I)]
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چکیده
منابع مشابه
Poly[di-μ-thiocyanato-κ2 N:S;κ2 S:N-bis[2-(1H-1,2,3-triazol-1-yl-κN 3)pyrazine]cadmium(II)]
In the title two-dimensional coordination polymer, [Cd(NCS)(2)(C(6)H(5)N(5))(2)](n), the Cd(II) ion (site symmetry ) is coordinated by two N atoms from two 2-(1H-1,2,3-triazol-1-yl)pyrazine ligands and two N and two S atoms from four thio-cyanate anions. The N-Cd bond lengths range from 2.323 (2) to 2.3655 (19) Å and the S-Cd bond length is 2.7117 (7) Å. The associated cisoid angles vary from 8...
متن کاملcatena-Poly[[(1,10-phenanthroline-κ2 N,N′)copper(I)]-μ-thiocyanato-κ2 N:S-[(1,10-phenanthroline-κ2 N,N′)copper(I)]-μ-cyanido-κ2 N:C]
In the title complex, [Cu(2)(CN)(NCS)(C(12)H(8)N(2))(2)], which was synthesized under hydro-thermal conditions, both Cu(I) atoms have a slightly distorted tetra-hedral geometry. They are coordinated by two N atoms of one 1,10-phenanthroline ligand, one bridging thio-cyanate anion and one bridging cyanide anion. In the crystal structure, infinite helical {Cu-CN-Cu-SCN}(n) chains are formed along...
متن کاملcatena-Poly[zinc-tris(μ-dimethylcarbamato-κ2 O:O′)-zinc-μ-(2-phenylbenzimidazolido-κ2 N:N′]
The crystal structure of the title compound, [Zn(2)(C(13)H(9)N(2))(C(3)H(6)NO(2))(3)](n), displays a long chiral chain. This is composed of zinc-dimer clusters capped by dimethyl-carbamate ligands, which lie on crystallographic twofold rotation axes and are polymerically linked in one dimension by 2-phenyl-benzimidadole (2-PBImi) organic ligands. The two Zn(2+) ions defining the dimetal cluster...
متن کاملBis(μ-2-phenoxypropionato-κ2 O:O′)bis[(1,10-phenanthroline-κ2 N,N′)bis(2-phenoxypropionato-κ2 O,O′)samarium(III)]
The dimeric title compound, [Sm(2)(C(9)H(9)O(3))(6)(C(12)H(8)N(2))(2)], is centrosymmetric and is composed of six 2-phen-oxy-propionate anions and two 1,10-phenanthroline ligands. The Sm(III) atom is coordinated by two O atoms from two bridging anions, four O atoms from two chelating anions and the N atoms of the N-heterocycle in a distorted dodeca-hedral geometry.
متن کاملμ-Squarato-κ2 O 1:O 2-bis{[2-(2-aminoethyl)pyridine-κ2 N,N′]aquanickel(II)} squarate 0.25-hydrate
The asymmetric unit of title compound, [Ni(2)(C(4)O(4))(C(7)H(10)N(2))(4)(H(2)O)(2)]C(4)O(4)·0.25H(2)O, contains one-half of a squarate ligand, one-half of an uncoordinated squarate dianion, two 2-(2-amino-ethyl)pyridine ligands and one aqua ligand, all coordinated to an Ni(II) ion. The compound also contains 0.25 solvent water mol-ecules. The Ni(II) ion has distorted octa-hedral geometry. The ...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2007
ISSN: 1600-5368
DOI: 10.1107/s1600536807007441